When Graphenemex® Graphene Transforms Dentistry: Stronger, Safer, and Antimicrobial PMMA

Posted on January 28, 2026 | by Energeia Graphenemex

When Graphenemex® Graphene Transforms Dentistry:

Stronger, Safer, and Antimicrobial PMMA

The world of dental materials is extensive and complex, encompassing a wide variety of materials from metals, ceramics, polymers, surgical, cements, impressions, and others, that have naturally progressed over time to provide greater mechanical functionality, aesthetics, biological, and/or microbiological performance.

In this evolutionary context, biomaterials science explores the use of graphene and its derivatives in dentistry due to their extraordinary theoretical properties: mechanical strength (Young’s modulus ~1 TPa), electrical conductivity (electron mobility >15,000 cm²/V·s), thermal conductivity (~5000 W/m·K), and chemical stability. These position graphene as an excellent candidate for developing restorative materials, bioactive cements, or those with improved adhesion or antimicrobial capacity, contributing to greater durability, better infection control, and long-term treatment success.

A widely used acrylic resin for manufacturing orthodontic and prosthetic appliances—and a research subject—is polymethyl methacrylate (PMMA). Due to its mechanical limitations and high contamination susceptibility, modifications have been evaluated, such as glass fiber, zirconia, titanium dioxide, graphene, and biocidal additives. Graphene stands out for its contributions to fracture resistance, dimensional stability, and reduced biofilm formation.

Biosafety is a primary concern for new materials. For graphene, this depends on its surface chemistry, concentration used, and whether particles are free or embedded in a polymer matrix, directly influencing interaction with surrounding tissues. In dental resins, toxicity often stems from leaching unreacted monomers and fillers, but this is mitigated by proper curing—via UV photopolymerization or thermal treatment—as per manufacturer specifications.

At appropriate concentrations, graphene leads to a denser polymer network, reduced monomer leaching, and improved biocompatibility. This enhances rigidity, compressive strength, and reduces wear rate for better durability through mechanisms such as:

Absorbing incident light to promote photo initiator radicals,

Facilitating energy or charge transfer to accelerate polymerization,

Providing nucleation sites for cross-links,

Reducing thermal expansion coefficient for long-term stability.

In Latin America, national graphene production and application are consolidating. In this scenario, the graphene produced by the Mexican company Energeia Fusion, under the brand Graphenemex®, since 2018 has undergone systematic studies for mechanical and antimicrobial properties in various materials. In 2023, the Nanomaterials Laboratory of the Master’s Program in Dental Sciences of the Faculty of Stomatology of the UASLP, incorporated it into research lines to analyze its effects in PMMA matrices, focusing on mechanical performance and biosafety in dentistry.

Investigations were conducted in two master’s projects directed by Dr. Juan Carlos Flores Arriaga, following ISO 7405 guidelines for biocompatibility evaluation of dental products and materials, and ADA No. 12 requirements for physical and chemical test methods of denture base resin materials.

Properties evaluated in PMMA modified with Graphenemex® graphene included:

1. Fracture resistance via stress, elasticity, and hardness analysis,

2. Characterization by microscopy (physical appearance), spectroscopy (molecular composition), and contact angle (liquid interaction changes),

3. Antimicrobial capacity against main caries causative Streptococcus mutans, and others like Streptococcus sobrinus and Streptococcus oralis, associated with caries and biofilm (dental plaque),

4. In vitro cytotoxicity assays on fibroblasts L-929 per ISO 10993-51.2009 (E) for medical device safety.

Experimental results confirmed that Graphenemex® graphene in PMMA caused no harmful chemical changes to polymeric integrity but significant improvements in mechanical performance — 90-150% over conventional PMMA — meaning less deformation during chewing, greater wear and fracture resistance.

Additionally, increased hydrophobicity (per contact angle), microbial growth inhibition (mainly S. mutans), and scanning electron microscopy observations confirmed enhanced antimicrobial capacity, anti-biofilm properties, and—crucially—no compromised biocompatibility, as cytotoxicity tests showed no toxicity across evaluated concentrations.

In conclusion, proper incorporation of Graphenemex® graphene endows PMMA with effective antimicrobial properties without toxicity, positioning it as a multifunctional dental biomaterial with mechanical, biological, and preventive advantages against oral biofilm-related pathologies. This supports its clinical potential in prosthetic rehabilitation, orthodontics, and orthopedics.

Writing: EF/Dania Hernández

Sources :

1. https://repositorioinstitucional.uaslp.mx/xmlui/handle/i/9563

https://repositorioinstitucional.uaslp.mx/xmlui/handle/i/8315

De Toledo, P.T.A.; Nunes, G.P.; Ferreira, M.F.; Martins, T.P.; Peres, G.R.; Soares, D.G.; Esteves-Oliveira, M. Bonding Behavior of Graphene-Based Enhanced Restorative Materials: A Systematic Review and Meta-Analysis. Int. J. Adhes. Adhes. 2025, 141, 104046.

Ben Ammar, T.; Roman, T.; Ba, H.; Ball, V.; Kharouf, N. Graphene and Related Materials: Properties and Applications in Dentistry. Materials 2025, 18, 5365. https://doi.org/ 10.3390/ma18235365

Saghiri, M.A.; Saini, R.S.; Kuruniyan, M.S.; Mosaddad, S.A.; Heboyan, A. Graphene and Its Modifications for Enhanced Adhesion in Dental Restoratives: A Molecular Docking and Dynamics Study. Sci. Rep. 2025, 15, 9455.

Janji´c, K.; Valentova, A.; Arellano, S.; Unterhuber, A.; Krause, A.; Oberoi, G.; Unger, E.; Tabrizi, H.A.S.; Schedle, A. The Impact of Print Orientation and Graphene Nanoplatelets on Biaxial Flexural Strength and Cytotoxicity of a 3D Printable Resin for Occlusal Splints. Dent. Mater. 2024, 40, 1742–1752.

Ahmad, K.H.; Mohamad, Z.; Khan, Z.I. Influence of Graphene Nanoplatelets and Post-Curing Conditions on the Mechanical and Viscoelastic Properties of Stereolithography 3D-Printed Nanocomposites. Polymers 2024, 16, 2721.

Graphene Toward 2036: Innovation, Market Growth, and the Future of Advanced Materials

Posted on January 12, 2026 | by Energeia Graphenemex

Graphene Toward 2036:

Innovation, Market Growth, and the Future of Advanced Materials

Since the late 2010s and early 2020s, graphene—widely regarded as the material of the future—has moved beyond the guarded walls of research laboratories to become a commercial reality. Although cost remains a limiting factor for large-scale adoption, numerous companies around the world have made strong commitments to this technology.

Recent Developments

Research on graphene is continuously evolving, generating ongoing advancements in production methods, material properties, and applications. Significant progress has been reported in the energy sector and in industries such as electronics, where graphene is expected to revolutionize the design of faster and more efficient devices. In medicine, it shows strong potential for early diagnostic tools, drug delivery systems, and tissue engineering. Additionally, graphene is enabling novel industrial applications that promote sustainability and the development of lighter, stronger materials.

Market Projections Toward 2036

According to studies by Market Research Future and Fortune Business Insights—global market research and consulting firms—the graphene market is expected to grow at a considerable rate in the coming years, reaching a valuation of several billion dollars by 2036. This growth will be driven primarily by demand from the electronics, energy, and composite materials sectors.

British firm IDTechEx, a leader in research on emerging and disruptive technologies, also forecasts accelerated growth in commercial graphene applications, particularly in sustainable technologies such as graphene-based batteries and supercapacitors, which are expected to deliver superior performance compared to current solutions.

Leading Companies in Graphene Development

Major technology companies such as Samsung and Huawei have invested significant resources in graphene research. Samsung, through the Samsung Advanced Institute of Technology (SAIT), has focused primarily on graphene-enhanced lithium batteries, aiming to increase capacity by up to 45% and charging speed by as much as five times. Huawei, meanwhile, has concentrated on graphene’s heat dissipation capabilities, which are critical for maintaining the performance of smartphones and tablets.

The multinational mining company BHP, through BHP Mitsubishi Alliance (BMA), signed an agreement to test a graphene-based coating under the ecosparc® brand by Sparc Technologies at its coal handling and processing facilities at the Goonyella Riverside mine in Queensland. The objective is to gather data on performance under extreme corrosion conditions.

Similarly, the Spanish multinational energy and petrochemical company Repsol has invested in Graphenea—one of the most well-known graphene companies—to advance research in batteries, thermal coatings, and other materials aimed at improving energy efficiency and developing new applications.

Other notable players include Luxembourg-based OCSiAl, which specializes in the synthesis of graphene nanotubes and offers performance-enhancing additives under the TUBALL™, TUBALL™ MATRIX, and TUBALL™ BATT brands. The Australian company First Graphene, known for its PureGRAPH® product line, supplies graphene raw materials and masterbatches for product development.

In Latin America, the most prominent company is Energeia Fusion (Mexico), which operates under the Graphenemex® and Graphenergy® brands. The company supplies graphene and graphene oxide as raw materials for new product development and creates applications for the construction, coatings, and plastics industries. In parallel, it collaborates with universities to promote multiple research lines, achieving notable results in dentistry, batteries, and conductive coatings. Energeia Fusion also offers consulting services for companies interested in integrating graphene technology into their products or services.

Other companies in the Americas include ACS Material and NeoGraf (USA), UCSGraphene and Gerdau Graphene (Brazil), and Graphenestone (Spain). El grafeno representa una de las innovaciones más emocionantes en el ámbito de materiales avanzados, con el potencial de revolucionar múltiples industrias.

Conclusion

Graphene represents one of the most exciting innovations in the field of advanced materials, with the potential to transform multiple industries. Market projections are highly promising, and an increasing number of companies are recognizing the value of this material. As research and development continue to advance, it is increasingly likely that graphene will become an integral part of everyday life soon.

Written by :EF/DHS

References:

One Atom Thick, Maximum Sensitivity: Graphene to Protect the Air We Breathe

Posted on November 21, 2025 | by Energeia Graphenemex

One Atom Thick, Maximum Sensitivity:

Graphene to Protect the Air We Breathe

Environmental monitoring is essential for understanding air quality and, consequently, for designing policies that protect both human health and the surrounding environment. However, current measurement tools still present technical, operational, and economic limitations that affect the accuracy and availability of data. For this reason, science continues to seek sensors that are not only more sensitive, but also portable, flexible, accessible, and capable of generating real-time, large-scale information. In this search, graphene and its derivatives have emerged as particularly promising materials.

“According to the World Health Organization (WHO), 99% of the global population breathes air that exceeds recommended quality limits.”

Properties of Graphene

Graphene is a one-atom-thick carbon nanostructure arranged in a hexagonal lattice that, in theoretical terms, has a surface area that can exceed 2600 m²/g and electron mobility greater than 15,000 cm²/V·s. These characteristics are responsible for its high sensitivity to surface changes, enabling it to detect minimal variations when gases or other molecules are adsorbed onto it.

Unlike conventional metal-oxide sensors that require high temperatures to operate, graphene-based sensors not only improve sensitivity but can also function at room temperature, reducing energy consumption and facilitating their integration into portable devices or smart textiles, as discussed in the article Graphene Wearables: The New Frontier Between Technology, Health, and Materials Science.

The Evolution of Graphene for Environmental Monitoring

The foundations for using graphene to design high-sensitivity sensors were established by scientists André Geim and Konstantin Novoselov from the University of Manchester, who received the 2010 Nobel Prize in Physics for isolating this material in 2004. Among their many discoveries, they demonstrated that graphene could respond to extremely small variations in its electronic environment and was even capable of detecting the presence of a single adsorbed atom or molecule of gas.

These discoveries opened a new landscape for environmental monitoring and accelerated research on graphene. Soon after, it was shown that, for the first time, a material only one atom thick could register electronic variations associated with gases such as nitrogen dioxide (NO₂), ammonia (NH₃), and volatile organic compounds (VOCs), with greater sensitivity than conventional sensors.

“The potential of graphene as a highly efficient sensor lies in its interaction with gases, which modifies its electrical properties, enabling more precise and sensitive detection.”

Recent Advances in Graphene for Environmental Monitoring

Below are several recent research results that illustrate the progress of graphene in the field of environmental monitoring:

2025-Mexico

Researchers at the Advanced Nanotechnology Laboratory of the Center for Scientific Research and Higher Education of Ensenada (CICESE), Baja California, Mexico, presented the results of an experimental–computational study on the detection mechanisms of a titanium dioxide (TiO₂)–graphene hybrid for LP gas detection.

The hybrid, prepared using the atomic layer deposition (ALD) technique — which allows precise ultrathin films of just a few nanometers — showed a clear electrical response to the gas, surpassing the limitations of pure TiO₂ such as high operating temperature and low selectivity. It displayed significant improvements in sensitivity and response speed compared to conventional sensors.

2025-China

Scientists at Guangxi Normal University in Guilin used a one-step hydrothermal method to develop a graphene–copper oxide (CuO) hybrid sensor for detecting hexanal, a volatile organic compound related to environmental pollution.

The new sensor exhibited a resistance change (response) of up to 26% at 100 ppm of hexanal at room temperature, maintaining performance across multiple test cycles and showing minimal interference from other gases — indicating good selectivity.

2022-India

Researchers from the Institute of Chemical Technology, the Bhabha Atomic Research Centre (BARC), and the Homi Bhabha National Institute developed a carbon-nanotube/graphene oxide (GO) aerogel for detecting VOCs associated with cancer.

The hybrid material tripled sensitivity with a detection limit of 70 ppb — much lower than the typical range of commercial metal-oxide sensors.

The favorable response of GO is attributed to the oxygen-containing groups (~16%) in its structure; however, if the oxygen content is too high (~30%), sensitivity drops significantly because the material becomes more insulating. Moreover, humidity (~60%) can artificially increase the signal, which is why graphene and reduced graphene oxide (rGO) often perform better according to other studies.

2019-Spain

The Nanosensors and Smart Systems (NOySI) group at the Spanish National Research Council (CSIC) prepared resistive sensors made from graphene, graphene oxide (GO), and reduced graphene oxide (rGO) using drop-casting and electrospray techniques on polymeric and silicon substrates.

These sensors were evaluated for their detection of pollutant gases such as NO₂ and O₃ at room temperature.

A key conclusion — consistent with other studies — is that not all graphenes behave the same. Their performance depends on their concentration and deposition method.

GO, being insulating, showed resistance so high that measurement was impossible.

Graphene and rGO, on the other hand, showed detectable responses starting from just 1 µg.

2015-Finland

Researchers from the Department of Micro and Nanosciences at Aalto University, in collaboration with various institutions, developed a prototype epitaxial graphene sensor that detected nitrogen dioxide (NO₂) at concentrations as low as 1 ppb — significantly more sensitive than commercial metal-oxide sensors, which typically require concentrations above 5–10 ppb for reliable signals.

This improved detection limit, combined with room-temperature operation and nearly zero energy consumption, highlighted the advantages of graphene over traditional materials that require operating temperatures between 150 and 400 °C.

Conclusion

This brief timeline shows how graphene is gradually and solidly establishing itself as an important tool for environmental monitoring.

While most sensors detect gases at concentrations on the order of parts per million (ppm), graphene-enhanced sensors can increase sensitivity to tens of parts per billion (ppb), with the added advantage of room-temperature operation.

However, despite these advantages, widespread commercialization may still take time. It is still necessary to optimize recovery times, minimize the variability caused by ambient humidity, and develop scalable and reproducible production processes suitable for real-world conditions.

Written by: EF/DHS

Referencias

Rodríguez Hueso, J.E. 2025. Estudio experimental-computacional de los mecanismos de detección del híbrido TiO₂–GR en presencia de gas LP. Tesis de Doctorado en Ciencias. Centro de Investigación Científica y de Educación Superior de Ensenada, Baja California. 87 pp.

Xiaoni Wei. 2025 J. A room-temperature hexanal gas sensor based on graphene/copper oxide composite. Phys.: Conf. Ser. 3084 012028.

Biranje, P. M., et. al. 2022. Ultra-fast detection and monitoring of cancerous volatile organic compounds in environment using graphene oxide modified CNT aerogel hybrid gas sensor. Sensors and Actuators B: Chemical, 375, 132934.

Sanz Montero, Irene. 2019. Preparación de sensores de gases basados en grafeno para la detección de contaminantes atmosféricos. Trabajo Fin de Grado / Proyecto Fin de Carrera, E.T.S.I. Industriales (UPM), Escuela Técnica Superior de Ingenieros Industriales.

Novikov, S., et. al. 2055. Graphene Based Sensor for Environmental Monitoring of NO2. Procedia Engineering, 120, 586-589

Graphene Wearables: The New Frontier Between Technology, Health, and Materials Science

Posted on November 10, 2025 | by Energeia Graphenemex

Graphene Wearables:

The New Frontier Between Technology, Health, and Materials Science

Graphene has revolutionized wearable technology by enabling flexible and highly sensitive sensors capable of monitoring medical parameters in real time. This nanomaterial stands out for its piezoresistive properties, allowing it to detect movement and pressure without sacrificing comfort. Moreover, its versatility enables interaction with a wide range of materials, enhancing the conductivity and flexibility of wearables. Among these materials, polymers, metallic nanoparticles, and other carbon-based compounds play a central role. Finally, the production of graphene involves various methods, and its properties can be optimized through combinations with other materials.

At the beginning of the 21st century, wearable technology seemed like a concept from science fiction. However, growing awareness of health and wellness accelerated its evolution to the point that today, wearables are not only real devices but, for many users, essential items—particularly in the medical field, where some wearables can monitor key parameters such as glucose, oxygen, or heart rate for real-time medical tracking. It is expected that, in the near future, these devices will go beyond data collection; with the integration of artificial intelligence, they will also interpret and provide personalized recommendations to address specific situations. Naturally, this progress also brings ethical and security concerns that must be properly addressed and safeguarded.

Graphene-Based Wearables

Strictly speaking, graphene is a nanomaterial composed of one or several layers of carbon atoms arranged in a hexagonal lattice. In practical terms, these structural characteristics allow it to act as an excellent piezoresistive material, as its electrical resistance can vary significantly under mechanical deformation.

“When a graphene sensor is stretched or deformed, the distance and overlap between its carbon atoms change, altering electron mobility and consequently its electrical resistance. This effect, known as piezoresistance, forms the basis for detecting forces, pressures, and movements in flexible sensors used in wearables.”

Thanks to its excellent ability to interact with various materials, graphene serves as an ideal base for developing sensors capable of detecting motion, temperature, or pressure without compromising comfort or flexibility in the garments that incorporate it.

What Materials Interact Well with Graphene?

Graphene is an extremely versatile material capable of interacting through covalent bonds, π–π interactions, Van der Waals forces, or hydrogen bonding, depending on the type of material it is combined with — including metals, ceramics, biomaterials, and polymers, among others.

In wearable technology, graphene exhibits excellent compatibility with polymers such as thermoplastic polyurethane (TPU), which allows materials to stretch, bend, or be washed without losing conductivity; with metallic nanoparticles like gold and silver, which enhance conductivity while maintaining flexibility; with carbon nanotubes, which help form a more stable and motion-sensitive network; and with other carbon materials such as carbon black, which fosters the creation of a hybrid conductive network acting as a bridge between graphene sheets, improving resistance sensitivity when the structure is deformed.

How Is a Graphene Wearable Manufactured?

The first step in manufacturing these products is to synthesize or produce graphene, either by chemical vapor deposition (CVD), mechanical exfoliation, or chemical oxidation. It is important to note that graphene produced by each of these methods has distinct characteristics, making it essential to understand their technical capabilities. Additional functionalization with other materials can also be considered to enhance performance.

Once the graphene material—with or without modifications—is ready, the next step is to integrate or immobilize it within a flexible matrix such as polydimethylsiloxane (PDMS) or polyurethane (TPU). This allows the sensor to be applied as a thin film on another substrate (e.g., textile) and connected via electrodes to electronic circuits for signal acquisition and processing. When in motion, the sensor deforms, changing its electrical resistance and converting this into digital data to monitor movement, pressure, and other parameters.

Research Advances in Graphene Wearables

2025 – University of Cambridge, together with the Capital Medical University and Beihang University (China), developed a graphene-based system for sleep monitoring integrated into washable, skin-compatible smart garments. The system detects laryngeal vibrations through a six-channel strain sensor matrix placed on a neck fabric to recognize and analyze sleep patterns.

2022 – University of Pennsylvania, researchers developed a PDMS-graphene patch for body temperature monitoring, achieving a 24% improvement in thermal conductivity. Combined with a data analysis software for smart terminals, it enabled real-time health monitoring with strong potential for public health applications, such as during the COVID-19 pandemic.

2021 – Wuhan University (China), scientists from the School of Mechanical and Power Engineering created flexible graphene and carbon black sensors with high sensitivity, stability, and excellent strain-to-resistance ratios.

2019 – Graphene Flagship & Institute of Photonic Sciences (Spain), presented one of the first graphene-based wearable prototypes using quantum dots to measure multiple vital signs (e.g., heart rate, respiratory rate, oxygen saturation, UV exposure) through flexible optics, demonstrating graphene’s potential in ultra-light and comfortable optical sensors.

2017 – Tsinghua University & Shanghai Jiao Tong University (China), developed an ultrathin neck device capable of detecting vocal cord movements and emitting sound. Notably, this prototype showed relative resistance changes up to ~150% at ~133 Ω and produced ~75 dB sound output at 0.38 W from a 2 mm distance.

2017 – Sabancı University (Turkey), the Center for Research and Application of Nanotechnology developed a smart garment with graphene textile electrodes for wrist and neck biopotential (ECG) monitoring. Compared to conventional electrodes, the graphene prototype achieved near-clinical performance with superior comfort.

Commercial Developments

Although most research remains at the experimental or prototype stage, several companies have already crossed the threshold from laboratory to market:

GraphWear (USA): Developed a non-invasive graphene-based glucose monitoring wearable, consisting of a thin graphene film attached to the back of a smartwatch or as an adhesive patch worn on the abdomen.

Graphene Newton (India): Launched a line of uniforms and wearables with graphene for health, location, and military performance monitoring.

Versarien (UK): Through its Graphene-Wear™ technology, offers enhanced thermal transfer, superior moisture management, and faster drying while maintaining air and vapor permeability. Recently, it obtained OEKO-TEX® certification, confirming that Graphene-Wear™ is a sustainable technology that meets legal and industry standards without posing risks to human health.

Written by: EF/DHS

References

Y. Chen et al., “Graphene-based wearable piezoresistive physical sensors,” Materials Today, vol. 36, pp. 158-179, 2020. DOI: 10.1016/j.mattod.2019.12.004

K.-Y. Chen, Y.-T. Xu, Y. Zhao et al., “Recent progress in graphene-based wearable piezoresistive sensors: From 1D to 3D device geometries,” Mater. Sci. Eng., 2023.

M.K.H. Chowdhury et al., “Sensing the future with graphene-based wearable sensors,” Sci. Rep., 2024.

F. Saeedi et al., “Recent Advances of Graphene‐Based Wearable Sensors,” Adv. Mater. Interfaces, 2025.

R. Huang et al., “Highly Stretchable and Sensitive SBS/Graphene Composite Fiber for Strain Sensors,” Compos. Sci. Technol., 2019.

J. Li et al., “Flexible, Highly Sensitive, and Wearable Pressure and Strain Sensors with Graphene Porous Network Structure,” ACS Appl. Mater. Interfaces, 2016.

Flexible graphene photodetectors for wearable fitness monitoring.’ Polat et al., Sci. Adv. 2019; 5: eaaw7846.

Huang J, Huang D. Graphene-Enhanced Polydimethylsiloxane Patch for Wearable Body Temperature Remote Monitoring Application. Sensors (Basel). 2022 Dec 2;22(23):9426.

Yapici MK, Alkhidir TE. Intelligent Medical Garments with Graphene-Functionalized Smart-Cloth ECG Sensors. Sensors (Basel). 2017 Apr 16;17(4):875. doi: 10.3390/s17040875. PMID: 28420158; PMCID: PMC5424752.

L. Ma, Y. Gao, S. Li, X. Lei, X. Li and F. Liu, “Flexible piezoresistive sensors with 3D CB/graphene conductive networks,” 2021 5th IEEE Electron Devices Technology & Manufacturing Conference (EDTM), Chengdu, China, 2021, pp. 1-3,

Aznar, P.R.D.; Junior, H.L.O. Advances and Applications of Graphene-Enhanced Textiles: A 10-Year Review of Functionalization Strategies and Smart Fabric Technologies. Textiles 2025, 5, 28

https://graphene-flagship.eu/about/first-10-years/spearheads/c2-sh06-weargraph

https://www.graphene-info.com/researchers-develop-graphene-based-intelligent-wearable-artificial-throat

https://www.graphene-info.com/graphwear-closes-205m-series-b-needle-free-graphene-powered-glucose-monitor

https://graphene-newton.com/service/smart-wearables-uniforms

From Amorphous Carbon to Graphene: Challenges in Producing Graphenic Materials from Waste

Posted on October 14, 2025 | by Energeia Graphenemex

From Amorphous Carbon to Graphene:

Challenges in Producing Graphenic Materials from Waste

Graphene is recognized as the fundamental structural unit of graphite. However, unlike graphite—which is a three-dimensional (3D) material—graphene consists of a single two-dimensional (2D) layer of carbon atoms arranged in a hexagonal lattice that gives it remarkable mechanical, thermal, electrical, and barrier properties, making it extremely attractive for scientific and technological applications.

Since graphene is composed primarily of carbon, its production typically relies on high-purity carbon sources such as graphite and even gases like methane, using methods such as liquid-phase exfoliation, chemical oxidation, or chemical vapor deposition (CVD). However, in the search for more sustainable, economical, and scalable production routes—particularly for industrial use—alternative carbon sources such as biomass and plastic waste have emerged.

The main challenge is that these processes initially produce amorphous carbon, a disordered form of carbon with low conductivity and without the intrinsic properties of graphene. Therefore, it is crucial to determine whether the materials produced are truly graphene or rather other less-ordered carbon-based structures with different properties.

“Each year, approximately 140 billion tons of agricultural biomass, 181.5 billion tons of forest and agricultural residues, and around 464 million tons of plastic waste are generated worldwide, of which only 20% is recycled, 25% is incinerated, and 55% ends up in landfills.”

Graphene from Biomass

Biomass is organic matter of animal or plant origin, including tree branches, agricultural or forestry residues, and biodegradable fractions of waste, among others. Its composition—rich in carbon, hydrogen, and oxygen—makes it a promising feedstock for producing graphene through thermal processes such as pyrolysis, gasification, and hydrothermal carbonization.

Recent studies have shown that, by using metallic catalysts such as manganese nitrate and maintaining precise temperature control, it is possible to directly convert biomass into graphitic carbon, meaning a graphene-like structure, while avoiding the formation of intermediate amorphous carbon. The key to success lies in carefully controlling the process to promote graphitization during pyrolysis and avoid incomplete carbonization that leads to amorphous carbon formation.

Graphene from Plastic Pyrolysis

Pyrolysis—the decomposition of chemical compounds through heat in the absence of oxygen—when applied to plastic waste, can yield fuels such as gasoline, diesel, and, in this case, graphene. For this process, catalysts such as potassium hydroxide (KOH), metal salts, or clays are required to break polymer bonds and promote carbon rearrangement into the characteristic flat aromatic structure of graphene.

An example of this is Flash Joule Heating (FJH), a process in which plastic materials are heated to extremely high temperatures in a fraction of a second, producing a turbostratic graphene-like material composed of multiple disordered stacked layers.

What Is Really Produced?

To achieve true graphene using these methods, it is essential to employ catalysts that promote graphitization, maintain rigorous thermal control, and apply additional steps for exfoliating and stabilizing the resulting graphenic sheets. If these conditions are not met, the product is likely to be amorphous carbon, which, although useful in certain applications, lacks graphene’s distinctive properties.

“Amorphous carbon lacks a repeating atomic pattern throughout the material, whereas turbostratic graphene exhibits partial hexagonal layer ordering.”

Conclusion

While producing graphene from biomass and plastic waste is indeed a promising route for utilizing waste and reducing environmental impact, the main challenges lie in ensuring the quality and purity of the resulting product as well as to control the CO₂ emissions.

These materials often contain a higher density of defects and, in some cases, may consist of a mixture of graphene, partially oxidized graphene, and amorphous carbon. The key is to properly identify and harness each material according to its distinct characteristics and properties.

Written by:EF/DHS

References

Mensah, R. A., et al. (2025). The facile conversion of waste biomass into few-layer graphene oxide without the formation of an amorphous intermediate. Scientific Reports, 15, Article 12345;

Saha, J. K., & Dutta, A. (2021). A Review of Graphene: Material Synthesis from Biomass Sources. Materials, 14(18), 5384;

Le, P. A., et al. (2025). A review of commercial plastic waste recycling into graphene-based materials: efficiency, challenges, and perspectives. RSC Advances, 15, 12345-12368;

Wyss, K. M., et al. (2021). Converting plastic waste pyrolysis ash into flash graphene. Carbon, 183, 351-360;

Nagendran, S., et al. (2024). Sustainable production of graphene using biomass waste: a review. Journal of Cleaner Production, 387, 135833; 6. Seah, C. C., et al. (2023). Co-pyrolysis of biomass and plastic: Circularity of wastes and comprehensive review of synergistic mechanism. Results in Engineering, 19, 100884.

Graphene Nanotechnology: Transforming Glass into a Multifunctional Material

Posted on September 19, 2025 | by Energeia Graphenemex

Graphene Nanotechnology:

Transforming Glass into a Multifunctional Material

Glass is a well-known material extensively used in architecture, automotive, electronics, energy, packaging, and even kitchenware. Among all glass types, the most common is float or annealed glass, but it is also the weakest and least safe, since when it breaks, fragments tend to be small, sharp, and therefore dangerous. For this reason, and for applications requiring greater strength or safety, manufacturing methods such as thermal tempering, ceramic coatings, or polymer lamination are employed, in addition to tinting, etching, and other processes.

Although conventional glass adequately meets market needs and might appear to require no further modification, it is worth considering emerging technologies such as graphene nanotechnology, which, if implemented correctly, could add significant value not only to glass but also to other materials and products, broadening and improving their fields of application.

What is graphene nanotechnology?

Graphene nanotechnology refers to the use of graphene—a nanoscale, sheet-like structure composed of extremely thin layers of carbon atoms strongly bonded in a honeycomb lattice—to develop new materials and applications. Since its isolation in 2004, research into its properties has opened a world of possibilities in science and technology, thanks to its extraordinary mechanical strength, lightness, flexibility, thermal conductivity, and electrical conductivity, among other characteristics. These properties not only exist in graphene itself but can also be transferred to other materials.

How can graphene properties be applied to glass?

The modification of glass with graphene nanoparticles is not entirely new; research has focused primarily on two main integration methods. The first involves applying graphene as a surface coating to increase resistance to scratching and abrasion. Reports indicate that ultrathin graphene films act as a transparent armor that disperses contact energy and reduces friction, improving scratch resistance by 30–40%.

The second approach involves incorporating graphene into the polymers used in lamination. In this case, graphene reinforces the intermediate polymers that bond different glass layers, improving adhesion and enabling the dissipation of 25–30% of impact energy.

It is also worth mentioning a third, less explored or documented approach: the integration of graphene throughout the entire glass matrix. Unlike applying it only on surface or intermediate layers, this method distributes graphene as a nanofiller both within and across the glass.

What is the added value of graphene as a nanofiller in glass?

Beyond improving mechanical performance when distributed throughout the matrix, graphene’s multifunctionality in terms of electrical conductivity, radiation resistance, and chemical barrier properties could also enable:

i) The development of smart glass (heatable, anti-fogging, or regulating heat and light transmission);

ii) Reduction of interior temperatures in automobiles, homes, or buildings;

iii) Mitigation or delay of degradation in materials and furnishings exposed to solar radiation;

iv) Enhanced anti-adhesive properties (e.g., resistance to dust, scale, and biofilms).

A key point is achieving all these benefits without compromising glass transparency, which remains essential in most of its applications.

Conclusion

Graphene represents a promising path toward transforming glass into not only a stronger and safer material but also a smart and multifunctional one. While the implementation of this technology has faced cost and scalability barriers, advances in production and technological development demonstrate that its incorporation—not only in glass but also in many other materials and composites—is increasingly feasible.

Drafted by: EF/DHS

References

Zhu, Y. et al. (2022). Role of graphene in enhancing indentation and scratch properties of glass. Surface & Coatings Technology.

Ali, A. et al. (2023). Polyvinyl butyral/Graphene Oxide Composite Coating for Enhanced Mechanical and Barrier Properties. Journal of Coatings Technology and Research.

Li, J. et al. (2023). Superlubricity and stress-shielding of graphene enables ultra scratch-resistant glasses. Nature Communications.

Kumar, R. et al. (2024). Effect of Graphene Oxide Nanoparticles on Polymer Interlayers for Laminated Glass Applications. Polymer Composites.

Ashfaq, J. et al. (2023), Enhancement of Thermal and Gas Barrier Properties of Graphene Based Nanocomposite Films. ACS Omega

Performance of Reinforced Concrete with Polymeric Macrofibers and Graphene Oxide: Results Report Graphenergy® Construction

Posted on August 25, 2025 | by Energeia Graphenemex

Performance of Reinforced Concrete with Polymeric Macrofibers and Graphene Oxide:

Results Report Graphenergy® Construction

Polymeric macrofibers are small filaments of strong synthetic material dispersed throughout the concrete mix to reinforce it from within. Their random distribution creates a discontinuous and homogeneous three-dimensional reinforcement effect that enhances the concrete’s toughness and ductility at every point of the structure.

The materials commonly used for the manufacture of this type of product include polypropylene, polyethylene, polyester, or nylon in different gauges or dimensions. These are highly effective for the reinforcement of pavements and roads, slabs, precast elements, shotcrete, and in some cases, may even substitute welded wire mesh. Given the wide variety of products, it is important to seek proper advice before use and to consider that macrofibers do not always increase the compressive or flexural strength of concrete, as they are mainly used for microcrack control. Therefore, they are not intended as a full replacement for structural reinforcement such as steel.

The Mexican company Energeia–Graphenemex®, through its polymer division, integrated the multifunctionality of graphene oxide to launch Graphenergy® Polymeric Macrofibers in order to enhance concrete performance under intense stresses.

Graphenergy® polymeric macrofibers represent an innovation in secondary three-dimensional reinforcement for concrete thanks to the integration of polymers and graphene oxide in their formulation. Unlike conventional fibers, the nanotechnology-based design and wavy surface of these macrofibers significantly improve their performance within the concrete.

“Graphene oxide is one of the most promising materials for enhancing the properties of a wide range of polymers. It consists of graphene—or pure carbon—sheets stabilized with oxygen-containing groups, resulting in a versatile structure that is water-compatible, adherent to cement crystals, and easily combinable with other compounds to design materials with new or improved properties.”

Why use graphene oxide in the production of synthetic macrofibers?

Enhances the mechanical properties of polymers, thereby increasing the resistance of each fiber under loads.

Improves fiber compatibility with concrete, resulting in excellent dispersion within fresh concrete.

Generates a better fiber–cement interface, improving fiber anchorage within hardened concrete.

Evidence-Based Science

As evidence of the benefits that synthetic macrofibers with graphene oxide offer concrete, the following results are presented from a study conducted to analyze the performance of concrete reinforced with different dosages of Graphenergy® Macrofibers at 7 days.

It is important to note that the standards and limits applied were defined according to the requirements of a specific project; therefore, the reported information is for reference purposes only.

How is fiber-reinforced concrete evaluated?

The most relevant tests focus on determining how fibers improve the strength and toughness of concrete, particularly after cracking occurs.

ASTM C78 is used to determine the flexural strength of plain concrete (without fibers), measuring how much force concrete can withstand in bending before breaking.

ASTM C1609 is used to evaluate fiber-reinforced concrete, specifically its residual strength once the first crack appears, as well as its behavior under further loading or tensile forces.

Materials Used

The materials were selected in compliance with applicable standards according to the mix design and project limits, including: sand, gravel, Type II cement, water, a water-reducing admixture, and the key variable of this study: Graphenergy® synthetic macrofibers at a dosage of 35,000 to 47,000 fibers per m³ of concrete.

Results Table

Interpretation

Modulus of Rupture

Before the appearance of the first crack, concrete dosed with Graphenergy® macrofibers resisted between 36 and 41 kg/cm², meeting the specification for reasonably strong flexural concrete. It is worth noting that this test is relatively independent of fiber presence, as it depends more directly on cement paste, aggregates, and curing. As expected, the fibers did not significantly influence these results. However, the fact that the specification was met is an indication of proper fiber distribution in the mix.

Minimum Equivalent Flexural Strength Ratio 𝑅D𝑇,150

This determination highlights the true contribution of macrofibers, as it measures the residual strength of concrete after cracking. According to specifications, concrete should retain at least 21% of its original strength. Remarkably, Graphenergy® macrofibers enabled the concrete to retain between 69% and 94%, depending on fiber dosage. This demonstrates that the fibers continue to work effectively even after cracking.

Minimum Residual Strength with Net Deflection L/150 fd150

This result reflects the post-cracking behavior of concrete in terms of crack control. The results shown in the table confirm the added value of macrofibers in improving early-age resistance, offering performance more than 300% above the specification (7.7 kg/cm²).

Conclusion

The study demonstrates that concrete reinforced with Graphenergy® Macrofibers not only meets but significantly exceeds project specifications. While not all properties show a linear correlation between fiber dosage and strength—such as modulus of rupture—the results clearly show substantial improvements in post-cracking capacity and toughness. These macrofibers emerge as a novel, highly recommended alternative for concrete reinforcement in applications subjected to impacts, cyclic loads, or where ductility is essential.

Prepared by: EF/DHS

Hydrogels and Graphene: The Technological Fusion Revolutionizing Materials Science

Posted on August 12, 2025 | by Energeia Graphenemex

Hydrogels and Graphene:

The Technological Fusion Revolutionizing Materials Science

Hydrogels are polymeric networks with a hydrophilic structure that allows them to retain large amounts of water in their three-dimensional networks. From their first references in 1900 to the advancements by Wichterle and Lim in the 1960s, hydrogel technology has evolved to become a vital solution in fields such as medicine (for controlled drug or bioactive agent delivery), environmental remediation (for contaminant adsorption or soil restoration), agriculture (for water retention or soil conditioning), food industry (from texturizing agents to smart packaging), and even energy storage, among others.

“In 1900, the term ‘hydrogel’ first appeared in scientific literature to describe a colloidal gel of inorganic salts.”

Hydrogels may be chemically crosslinked through covalent bonds, physically through non-covalent interactions, or via a combination of both. They are classified into natural (including proteins such as collagen and gelatin, and polysaccharides such as starch, alginate, and agarose), synthetic (produced through chemical polymerization methods), and hybrid hydrogels. Synthetic materials have largely replaced natural ones due to better water absorption, longer lifespan, and a broader variety of raw materials.

“The water absorption capacity of hydrogels is due to hydrophilic functional groups attached to their polymer structure, while their resistance to dissolution results from crosslinks between the network chains.”

Hydrogels are mainly known and used for their excellent water absorption capabilities without altering their structure. However, their low mechanical strength and sensitivity to external stimuli such as temperature, light, or electric fields can either enhance or limit their performance in dynamic environments. Some examples include:

Temperature Sensitivity: These hydrogels expand or contract in response to heat or cold, enabling them to release contaminants, drugs, or bioactive agents—ideal for wastewater treatment or medical therapies. Their challenges include long-term stability and precise temperature responsiveness.

Photosensitivity: The integration of photoactive agents into their polymer networks can improve contaminant degradation, activate and release specific drugs, or enhance cellular growth conditions in tissue engineering. However, continuous UV exposure may lead to photodegradation of the material.

Electric Field Sensitivity: Electroactive hydrogels incorporate ionic groups that move and alter the hydrogel’s structure under an electric field, modifying its permeability to allow or block the passage of substances. This is useful for wastewater treatment and controlled water or nutrient release in agriculture. High costs and limited durability remain key challenges.

pH Sensitivity: This is achieved by incorporating ionizable functional groups (carboxyl or amino), which gain or lose protons based on environmental pH, triggering structural changes that allow water absorption or release.

How Does Nanotechnology Enhance Hydrogel Performance?

Nanotechnology—the interdisciplinary field focused on manipulating and manufacturing materials at the atomic and molecular scale (1–100 nanometers)—has made significant contributions to hydrogels, particularly in improving mechanical strength and developing smart functionalities for biomedical and environmental applications.

“To understand the nanoscale, consider that the average thickness of a human hair is approximately 60,000 nm, while a nanometer is one-millionth of a millimeter.”

What Added Value Does Graphene Bring to Hydrogels?

Graphene is a nanometric, two-dimensional (2D) carbon sheet one atom thick, with a structure similar to a benzene ring. It has attracted significant research interest due to its exceptional properties: thermal conductivity, mechanical strength, flexibility, and biocompatibility, among others, which can be transferred to hydrogel matrices.

1. Mechanical Strength:

One of the key limitations of hydrogels is their low mechanical resistance, making them unsuitable for high-stress environments. Graphene can significantly reinforce hydrogel structure, improving durability and mechanical stability.

2. Thermal Stability:

Hydrogels are sensitive to temperature changes, which can affect their performance. Graphene can enhance their thermal stability, maintaining functional properties across wider temperature ranges.

3. Antimicrobial Protection and Biocompatibility:

While hydrogels are generally biocompatible, scientific evidence shows that adding graphene improves their stability and compatibility. Its intrinsic antimicrobial properties also make hydrogels safer for infection-sensitive applications.

4. Electrical Responsiveness:

Graphene’s ability to transmit electrical signals supports cell communication in electrically active tissues (e.g., nerve, muscle, heart). It also enables controlled drug release under voltage stimulation, while minimizing overheating during electrical activation.

Although there are no graphene-based hydrogels commercially available yet, many experimental nanotechnological developments around the world are laying the groundwork for future applications, including:

Spain (2025): A study by the Spanish National Research Council and the National Hospital for Paraplegics used a reduced graphene oxide (rGO) foam scaffold to reconnect severed spinal cords in rats, promoting neuronal reconnection and vascular regeneration.

Argentina (2025): The University of Buenos Aires, CONICET, and INTI developed hydrogels resistant to hydration-dehydration cycles for nanofiltration of viruses, bacteria, fungi, and heavy metals from water.

USA (2023): A study published in Environmental Science & Technology demonstrated that graphene-based hydrogels could remove up to 95% of lead ions from aqueous solutions.

China (2022): Biomaterials Translational published a study on a hyaluronic acid–graphene oxide hydrogel combined with Senexin A for treating vascular occlusive diseases, achieving sustained release over 21 days and good biocompatibility.

USA (2022): In Applied Materials & Interfaces, researchers reported a graphene hydrogel scaffold that promoted cartilage regeneration with type II collagen expression and stable cellular growth.

Spain (2018): Researchers at the University of the Basque Country developed a starch–graphene hydrogel for flexible brain implant electrodes. The graphene was stabilized in water using sage extract, which also added antibacterial and electrical properties.

USA (2017): A porous graphene oxide hydrogel developed for water purification showed enhanced contaminant adsorption due to improved stability, nanotransport channels, and hydrogen bonding.

USA (2017): A soft, injectable hydrogel made from PEGDA–melamine and GO improved cardiac function in rats with myocardial infarction, reducing infarct size and fibrosis while promoting neovascularization.

Conclusion

Graphene-based hydrogels, and those incorporating its derivatives, offer significant structural and functional improvements. Their development represents a leap toward smarter and more adaptive systems in biomedicine, agriculture, and environmental remediation. However, like any emerging technology, widespread adoption will require overcoming regulatory and large-scale manufacturing challenges.

Written by: EF/ DHS

References

Visan, A. I.; Negut, I. Environmental and Wastewater Treatment Applications of StimulusResponsive Hydrogels. Gels 2025, 11 (1), 72.

Yu, K.; Wang, D.; Wang, Q. Tough and SelfHealable Nanocomposite Hydrogels for Repeatable Water Treatment. Polymers 2018, 10, 880.

Lim, S. L.; Tang, W. N. H.; Ooi, C. W.; Chan, E.S.; Tey, B. T. Rapid swelling and deswelling of semiinterpenetrating network poly(acrylic acid)/poly(aspartic acid) hydrogels prepared by freezing polymerization. J. Appl. Polym. Sci. 2016, 133, 9.

Yuan, Z.; Wang, Y.; Han, X.; Chen, D. The adsorption behaviors of the multiple stimulusresponsive poly(ethylene glycol)based hydrogels for removal of RhB dye. J. Appl. Polym. Sci. 2015, 132, 42244.

Thakur, S.; Arotiba, O. Synthesis, characterization and adsorption studies of an acrylic acidgrafted sodium alginatebased TiO₂ hydrogel nanocomposite. Adsorpt. Sci. Technol. 2018, 36, 458–477.

Eraković, Z.; Stefanović, D. Purification of contaminated wastewater with the help of graphene composites with hydrogels. Facta Univ. Ser. Work. Living Environ. Prot. 2022, 19, 27–**.

Wu, R.; Tian, L.; Wang, W.; Man, X. Bifunctional cellulose derivatives for the removal of heavymetal ions and phenols: Synthesis and adsorption studies. J. Appl. Polym. Sci. 2015, 132, 41830.

Zheng, Y.; Zhu, Y.; Wang, F.; Wang, A. GelatinGrafted Granular Composite Hydrogel for Selective Removal of Malachite Green. Water, Air, Soil Pollut. 2015, 226, 354.

Malik, R.; Saxena, R.; Warkar, S. G. Organic Hybrid Hydrogels: A Sustenance Technique in WasteWater Treatment. ChemistrySelect 2023, 8, e202203670.

Berg, J.; Seiffert, S. Composite hydrogels based on calcium alginate and polyethyleneimine for wastewater treatment. J. Polym. Sci. 2023, 61, 2203.

Singh, R.; Datta, B. Advances in Biomedical and Environmental Applications of Magnetic Hydrogels. ACS Appl. Polym. Mater. 2023, 5, 5474.

Tang, S. C. N.; Yan, D. Y. S.; Lo, I. M. C. Sustainable Wastewater Treatment Using Microsized Magnetic Hydrogel with Magnetic Separation Technology. Ind. Eng. Chem. Res. 2014, 53, 15718.

Wahid, F.; Zhao, X.J.; Jia, S.R.; Bai, H.; Zhong, C. Nanocomposite hydrogels as multifunctional systems for biomedical applications: Current state and perspectives. Composites Part B: Engineering 2020, 200, 108208.

Bao, R.; Tan, B.; Liang, S.; Zhang, N.; Wang, W.; Liu, W. A ππ conjugationcontaining soft and conductive injectable polymer hydrogel highly efficiently rebuilds cardiac function after myocardial infarction. Biomaterials 2017, 122, 63.

Maturavongsadit, P.; Wu, W.; Fan, J.; Roninson, I. B.; Cui, T.; Wang, Q. Grapheneincorporated hyaluronic acidbased hydrogel as a controlled Senexin A delivery system. Biomater. Transl. 2022, 3 (2), 152–161.

Lyu, C.; Cheng, C.; He, Y.; Qiu, L.; He, Z.; Zou, D.; Li, D.; Lu, J. Graphene hydrogel as a porous scaffold for cartilage regeneration. ACS Appl. Mater. Interfaces 2022, 14 (49), 54431.

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Conductivity and Control: Graphene in the Evolution of Antistatic Materials

Posted on May 14, 2025 | by Energeia Graphenemex

Conductivity and Control:

Graphene in the Evolution of Antistatic Materials

In the early 18th century, scientists began to notice that some materials, when rubbed together, were mysteriously attracted to one another, while others—especially those of different natures—were consistently repelled. After many observations of the same phenomenon, researchers concluded that invisible fluids or charges were being transferred between certain objects, later described as attractive or repulsive forces.

It was Benjamin Franklin who proposed that only one type of fluid was exchanged between objects, and that differing charges resulted from an excess or deficiency of this fluid. Franklin tested this with wax and wool, observing that rubbing them caused the wool to extract the invisible fluid from the wax—leading to a surplus in the wool and a deficit in the wax. This imbalance would then generate attractive forces as the system sought to restore equilibrium.

“It was later discovered that this invisible ‘fluid’ was made up of tiny fragments of matter called electrons— the smallest known carriers of electric charge.”

Today, we understand that electric charge results from the transfer of electrons between bodies that generate electrostatic tension. However, in insulating materials like plastics, the charge remains static and localized at the point of contact. When such plastics encounter objects at different potentials—such as a person or an electronic microcircuit—static electricity may discharge via a spark or arc. This can damage electronic equipment or even trigger fires and explosions, especially in the presence of flammable substances. For this reason, the use of antistatic materials in construction products, electronics, storage centers, textiles, and many other applications is critical.

“Static charge is also known as static electricity or electrostatics.”

Plastics are found in nearly every environment. While they serve countless purposes, the static charge they accumulate can limit their use. This is why antistatic additives are often incorporated to reduce electrical resistance, making them suitable for producing antistatic packaging for electronics, automotive, or chemical industries. These materials may be biodegradable biopolymers like polylactic acid (PLA) and cellulose acetate (CA) or non-biodegradable petrochemical plastics such as polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET). Antistatic solutions are also used in construction supplies made from PVC or rubber, especially in chemical plants, gas stations, or coal mines.

How many types of antistatic additives are there?

The family of antistatic additives is broad. They include ionic, non-ionic, conductive polymers, phosphorus-based additives, and carbon-based materials. In this article, we focus on the latter—specifically, carbon black, graphite, and most notably, graphene.

“According to ASTM D257-78, the surface resistivity of antistatic materials ranges from 1.0×10⁵ to 1.0×10¹² Ω/sq.”

Graphene is a carbon nanostructure with exceptional electrical conductivity (0.96 × 10⁸ Ω·m⁻¹), making it a powerful antistatic agent. Unlike graphite—a 3D carbon structure made of millions of graphene layers—and carbon black, which is amorphous and tends to form large aggregates, graphene has a well-organized sheet-like structure with a high surface area accessible on both sides. This allows it to interact intimately with other molecules and modify the properties of many materials, particularly polymers—not only by reducing static, but also by enhancing mechanical strength, thermal resistance, and barrier properties.

Technically, graphene is composed solely of carbon atoms. But in practice, there are as many types of graphene as there are production methods—whether producing pristine graphene, graphene oxide (GO), or reduced graphene oxide (rGO)—each potentially functionalized during or after production. These functionalizations are often necessary to improve graphene’s interaction with specific polymer matrices and to impart desired properties, such as antistatic behavior.

To integrate graphene into PLA used in antistatic packaging, plasticizers like thymol, polyethylene glycol (PEG), or dibutyl sebacate (DBS) can serve as carriers—not just to reduce resistivity but also to enhance mechanical strength and barrier properties. Literature reports show that graphene in PLA can increase electrical conductivity from 1.39E-12 S/cm to 2.83E-4 S/cm. For antistatic rubber flooring, graphene can be functionalized with zinc methacrylate to reduce resistivity by up to three orders of magnitude.

Another critical factor is graphene’s proper dispersion and integration into the host matrix—something that varies depending on the material. For rubber, graphene can be functionalized with 3-glycidyloxypropyltrimethoxysilane, a coupling agent that bonds organic and inorganic materials. For PET, GO can be functionalized with p-phenylenediamine (PPD), which improves dispersion, thermal stability, and boosts antistatic performance by up to eight orders of magnitude.

In the case of cellulose acetate (CA), a biodegradable polymer gaining popularity in packaging, direct functionalization of graphene with CA molecules during synthesis improves both dispersion and static dissipation—lowering surface resistivity from 1.09×10¹² Ω/sq to 1.51×10⁹ Ω/sq. A similar strategy applies to PVC, using dioctyl phthalate (DOP), a plasticizer that can assist during graphite exfoliation to create a graphene more compatible with PVC and reduce resistivity from 10¹⁶ Ω-cm to 2.5 × 10⁶ Ω/sq.

Clearly, graphene represents a technological leap forward in the development of advanced plastics. Its capacity as an effective antistatic additive—along with its multifunctional benefits—makes it a key material for driving innovation in this field. However, its performance depends heavily on selecting the right type of graphene, the functionalization process, and its integration into the polymer matrix. As research continues, graphene is becoming an increasingly vital solution for meeting the safety, performance, and sustainability demands of the plastics industry.

Written by: EF/DHS

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